An XPS study of platinum nanoparticles prepared by a low-pressure flat flame
نویسندگان
چکیده
The one-step synthesis and characterization of nanostructured metallic platinum microspheres by a low-pressure flat flame technique is presented here. Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD) and X-ray Photoelectron Spectroscopy (XPS) analyzed the as-derived powders. Collectively, the results obtained from these analyses confirmed the formation of microspheres comprising closely packed metallic platinum nanoparticles of face center cubic structure. Nanoparticles contained within submicrometer to tens of nanometer microspheres as derived with 0.1 and 0.01M H2PtCl6 solution have a volume-averaged size of 14.59 and 12.20 nm as determined by XRD. The XPS analyses confirmed the composition of the surface layer of the microspheres to be metallic platinum.
منابع مشابه
Nanostructuring Platinum Nanoparticles on Ni/Ce0.8Gd0.2O2-δ Anode for Low Temperature Solid Oxide Fuel Cell via Single-step Infiltration: A Case Study
With the aim of promoting the Ni/Ce0.8Gd0.2O2-δ (Ni/GDC20) cermet anodic performance of low temperature solid oxide fuel cell (LT-SOFC) [1], nanostructuring platinum nanoparticles on NiO/GDC composite was done by single-step wet-infiltration of hexachloroplatinic acid hexahydrate (H2PtCl6.6H2O) precursor on NiO/GDC20 composite. The anodic polarization resistance was measured using symmetr...
متن کاملA green approach to the facile synthesis of colloidal platinum nanoparticles by Preyssler polyoxometalate
In the present study, platinum nanoparticles were synthesized through an effective, facile and green method using H14[NaP5W30O110], a Preyssler-structured polyoxometalate, under UV light irradiation. Preyssler plays the roles of photocatalyst, reducing agent and stabilizer in the synthesis of Pt nanoparticles. The effect of different parameters, i.e. time, propan-2-ol volume, pH, molar ratio of...
متن کاملIntroducing Pt/ZnO as a new non carbon substrate electro catalyst for oxygen reduction reaction at low temperature acidic fuel cells
Gas diffusion electrode was used for providing better conditions in fuel cell systems for oxygen reduction reaction (ORR). Because the slow kinetics of the oxygen reduction reaction at the proton exchange membrane fuel cell cathode restricts fuel cell efficiency. To this end, researchers have used platinum-coated carbon. In the present study, due to the reduction of carbon corrosion, Zinc oxide...
متن کاملIntroducing Pt/ZnO as a new non carbon substrate electro catalyst for oxygen reduction reaction at low temperature acidic fuel cells
Gas diffusion electrode was used for providing better conditions in fuel cell systems for oxygen reduction reaction (ORR). Because the slow kinetics of the oxygen reduction reaction at the proton exchange membrane fuel cell cathode restricts fuel cell efficiency. To this end, researchers have used platinum-coated carbon. In the present study, due to the reduction of carbon corrosion, Zinc oxide...
متن کاملX-ray spectroscopy studies on the surface structural characteristics and electronic properties of platinum nanoparticles.
The surface structural characteristics and electronic behavior of three platinum nanoparticle (NP) samples prepared with tertiary amine (Pt-TA), primary amine (Pt-PA), and thiol (Pt-SR) molecules were studied using Pt 4f, 5d, and S 2p x-ray photoelectron spectroscopy (XPS), Pt L(3)-edge x-ray absorption spectroscopy (XAS), and theoretical projected local density of states (l-DOS) calculations. ...
متن کامل